According to a report from xinmsn.com on 17 July 2014, Zhou Xun and her boyfriend, Chinese-American actor Archie Kao (CSI: Crime Scene Investigation actor), surprised everyone at the “One Night” charity gala in Hangzhou on 16 July 2014. The newlyweds exchanged their vows on stage, in front of a massive crowd, at a charity event that was organised by Zhou Xun. As Zhou Xun is turning 40 this year, her good friends revealed that she wishes to start a family soon.
Zhou Xun, met Archie in Hong Kong in 2013. She has been rumoured and romantically linked to Nicholas Tse before her relationship with Archie surfaced. She had also previously dated Li Yapeng who is currently divorced from Faye Wong.